Menthone
Menthone
Menthone
Menthone — Natural and Synthetic Grade Exporter from India
Zentish Exim Pvt Ltd supplies Menthone — in both natural and synthetic grades — to flavor houses, fragrance compounders, pharmaceutical formulators, and specialty chemical manufacturers across the United States. Menthone is a cyclic ketone and a key component of the mint oil family, occurring naturally in peppermint oil and cornmint oil and serving as an important synthetic building block for the production of menthol derivatives and flavoring compositions.
Buyers who specify Menthone as a standalone ingredient are typically working in one of two contexts: flavor and fragrance compounding where Menthone's distinctive minty-woody, slightly camphoraceous character is a desired component in a complex composition, or synthetic chemistry where Menthone serves as an intermediate for derivative synthesis. Understanding which context applies determines grade specification, purity requirement, and documentation needs — all of which we address below.
Product Overview
Menthone is the second most abundant component of peppermint oil, typically present at 14–32%, and a significant minor component of cornmint oil. Chemically, it is a monocyclic monoterpenoid ketone — the immediate biosynthetic precursor to menthol in the mint plant's metabolic pathway. In flavor terms, Menthone contributes a minty, green, slightly cooling, and somewhat woody note that is distinctly different from menthol's pure cooling character. It rounds out mint flavor compositions and adds complexity that straight menthol cannot provide.
Two isomers exist: L-menthone (the naturally predominant form, occurring in nature at approximately 95%+ of total menthone in peppermint oil) and D-isomenthone (the minor natural isomer). Commercial synthetic Menthone is typically supplied as a mixture with varying ratios depending on the synthetic route. Natural Menthone, isolated from mint oil fractions, delivers the naturally predominant L-isomer profile and is specified by buyers who need "natural" labeling compliance or who prefer the authentic mint character that the natural isomer ratio provides.
We supply natural Menthone isolated from cornmint and peppermint oil fractions, and synthetic Menthone (high purity, GC-confirmed) for buyers where synthetic origin is acceptable and cost efficiency is a priority.
Key Specifications
Menthone — Technical Data
Physical Properties
Menthone is a colorless to slightly pale yellow mobile liquid at ambient temperature. It has a lower boiling point than menthol and is more volatile, which has implications for handling during formulation — open vessels in warm environments will lose Menthone content measurably faster than they would lose menthol. Work in temperature-controlled environments and keep containers sealed until point of use.
The optical rotation value is one of the most useful quick-screen parameters for natural versus synthetic Menthone. Natural L-menthone from mint oil fractions will show a clear levorotatory rotation (-20° to -30°). Synthetic racemic Menthone will show near-zero rotation. If a supplier of "natural" Menthone shows near-zero optical rotation, the natural origin claim warrants scrutiny.
Physical State: Mobile liquid
Color: Colorless to slightly pale yellow
Boiling Point: 207°C
Flash Point: Approximately 71°C
Vapor Pressure: Higher than menthol at ambient temperature — handle with ventilation
Miscibility: Fully miscible with common organic solvents and carrier oils; insoluble in water
Stability: Stable under normal storage; avoid prolonged exposure to strong oxidants and high temperatures
Natural vs Synthetic Menthone — Choosing the Right Grade
The choice between natural and synthetic Menthone is driven by three factors: labeling requirements, flavor authenticity, and budget.
Natural Menthone
Isolated from cornmint or peppermint oil fractions during the distillation and processing chain. The L-isomer predominates at 90%+ of total menthone content, reflecting the natural botanical ratio. This grade qualifies for "natural flavor" declarations under FDA 21 CFR 101.22 and meets FEMA GRAS status. It is the specified grade for flavor compositions sold under natural labeling and for buyers whose end product marketing emphasizes botanical or natural ingredient sourcing.
Synthetic Menthone
Produced via chemical synthesis, typically from thymol or via hydrogenation of synthetic precursors. Purity is typically higher (98%+ GC) and the supply is not subject to seasonal variation in mint oil composition. It is cost-effective for industrial applications, chemical synthesis, and formulations where natural origin is not a labeling requirement. Optical rotation near zero distinguishes it definitively from natural grades.
Product Specifications
| CAS Number | 10458-14-7 (L-Menthone); 89-80-5 (racemic / mixtur |
|---|---|
| Botanical Name | Mentha arvensis |
| Extraction Method | Fractional Distillation / Synthetic Manufacturing |
| Grade | Natural (L-menthone dominant); Synthetic (high purity) |
| Purity / Assay | 95% minimum (natural); 98% minimum (synthetic) |
| Appearance | Colorless to slightly pale yellow mobile liquid |
| Odor | Minty, slightly woody, green, mildly cooling ÔÇô less intense than menthol |
| Optical Rotation | -20┬░ to -30┬░ (natural L-menthone); near zero (synthetic racemic) |
| Specific Gravity | 0.888 ÔÇô 0.895 |
| Refractive Index | 1.448 ÔÇô 1.453 |
| Flash Point | Approx. 71┬░C |
| Solubility | Miscible with ethanol, ether, oils; insoluble in water |
| Packaging | 180kg GI drums |
| Country of Origin | India |
| HS Code | 29142300 |
| FEMA Number | 2667 |
Industries Served & Applications
Pharmaceuticals
Cosmetics & Personal Care
Flavor & Fragrance